[1]闫小星,钱星雨,吴智慧.微胶囊型自修复技术及其在涂料中的应用[J].林业工程学报,2019,4(05):20-28.[doi:10.13360/j.issn.2096-1359.2019.05.003]
 YAN Xiaoxing,QIAN Xingyu,WU Zhihui.Self-repairing technology of microencapsulate and its applications in coatings[J].Journal of Forestry Engineering,2019,4(05):20-28.[doi:10.13360/j.issn.2096-1359.2019.05.003]
点击复制

微胶囊型自修复技术及其在涂料中的应用()
分享到:

《林业工程学报》[ISSN:1001-8081/CN:32-1160/S]

卷:
4
期数:
2019年05期
页码:
20-28
栏目:
专论综述
出版日期:
2019-09-16

文章信息/Info

Title:
Self-repairing technology of microencapsulate and its applications in coatings
文章编号:
2096-1359(2019)05-0020-09
作者:
闫小星钱星雨吴智慧
南京林业大学家居与工业设计学院,南京 210037
Author(s):
YAN Xiaoxing QIAN Xingyu WU Zhihui
College of Furnishings and Industrial Design, Nanjing Forestry University, Nanjing 210037, China
关键词:
微胶囊 涂料 微裂纹 自修复
Keywords:
microcapsules coatings micro-cracks self-repairing
分类号:
TQ639; TQ630
DOI:
10.13360/j.issn.2096-1359.2019.05.003
文献标志码:
A
摘要:
涂料在长期使用过程中会因环境因子、物理损伤或其他因素导致涂层内部产生微裂纹,降低其保护性能,从而影响使用期限、增加经济成本。为了修复裂纹或损伤,应用于涂料中可进行自修复的微胶囊技术成为了现在热门的研究方向。笔者首先根据囊芯材料不同,归纳了几种常见的自修复体系,并对各体系目前的研究进展、微胶囊制备原理以及未来发展等方面进行了总结。微胶囊型自修复体系主要包括双环戊二烯-Grubbs固化剂体系、环氧树脂芯材微胶囊自修复体系、异氰酸酯微胶囊自修复体系、干性油微胶囊自修复体系、极性溶剂芯材自修复体系、硅氧烷自修复体系和硅油型自修复体系等。现阶段自修复涂料的研究主要针对制备过程中的工艺因素优化,部分自修复体系在涂料领域实现广泛应用还比较困难。对制备微胶囊的常见方法进行了介绍,主要包括界面聚合法、原位聚合法、溶剂挥发法,需根据微胶囊应用领域、性能要求、成本和生产规模等因素共同决定制备方法。论述了微胶囊自修复技术在木器涂料、颜料和纺织印染,以及建筑、航空航天和船舶涂料中的应用,发现微胶囊技术研究应用越来越趋向专业化。最后,对微胶囊技术的发展趋势进行了展望,如优化现有自修复系统、改性微胶囊提升其修复作用等。
Abstract:
During the long term application of coatings, micro-cracks occur in the coating due to environmental influences, physical damages or other reasons, which would reduce the protective performance of coatings, affecting the life of coatings and increasing the cost.In order to repair the cracks or damages, the self-repairing technology of microencapsulate has become a hot research direction.According to the different core materials, this paper introduces several common self-repairing systems, and summarizes the current research progress of each system, the preparation principle of microcapsules, and the future development.The self-repairing system of microencapsulate mainly includes dicyclopentadiene-Grubbs curing agent system, epoxy resin core microcapsule self-repairing system, isocyanate microcapsule self-repairing system, dry oil microcapsule self-repairing system, polar solvent core self-repairing system, siloxane self-repairing system and silicone oil self-repairing system.At present, the research on self-repairing coatings is mainly aimed at the optimization of process factors affecting the preparation process, which is challengeable for some self-repairing systems to be realized a wide range of applications in the field of coatings.The common methods for preparing microcapsules are introduced, including interface polymerization, in-situ polymerization and solvent volatilization, which needs to be decided comprehensively according to the application field, performance requirements, cost and scale of production of microcapsules.This paper discusses the application of microcapsule self-repairing technology in wood coatings, pigments and textile printing and dyeing, as well as in building, aerospace and marine coatings.It is found that the microcapsule technology research and application have become more and more specialized.The future application and development prospects of microcapsule technology are proposed, such as the optimization of the existing self-healing systems and the improvement of its repair functions.In future studies, researchers are expected to focus on exploring the repair mechanism of microcapsules, enhancing the interfacial bonding force between microcapsules and matrix and the time-effectiveness of microcapsule repair.On the basis of satisfying self-repairing function, microcapsules are developed to improve other properties of coatings, such as the anticorrosion and hydrophobic properties of coatings.By considering the addition of the modifier, the polymer is enhanced with new nanoparticles such as graphene, which have excellent protective and mechanical properties.The microcapsules are expected to be developed for using in large quantities in the industrial production and helping the development of various industries through applying the microcapsule self-repairing technology.

参考文献/References:

[1] 曹坤丽, 吴燕, 于成宁, 等.纤维素纳米晶体/KH560对UV固化水性木器涂层性能的影响[J].林业工程学报, 2016, 1(2): 135-139.DOI: 10.13360/j.issn.2096-1359.2016.02.024.
CAO K L, WU Y, YU C N, et al.The influence of CNC and KH560 on the properties of waterborne UV-curable wood coatings[J].Journal of Forestry Engineering, 2016, 1(2): 135-139.
[2] 陶鑫, 毛泽南, 徐伟, 等.仿古涂饰工艺对改性杨木漆膜表面粗糙度的影响[J].林产工业, 2019, 46(6): 33-36.DOI: 10.19531/j.issn1001-5299.201906007.
TAO X, MAO Z N, XU W, et al.Effect of antique painting technology on film roughness of modified poplar[J].China Forest Products Industry, 2019, 46(6): 33-36.
[3] 崔锦峰, 周应萍.微胶囊技术在涂料中的应用[J].涂料工业, 2003, 33(11): 54-56.DOI: 10.3969/j.issn.0253-4312.2003.11.018.
CUI J F, ZHOU Y P.Application of microencapsulation technology in coatings[J].Paint & Coatings Industry, 2003, 33(11): 54-56.
[4] KESSLER M R, WHITE S R.Self-activated healing of delamination damage in woven composites[J].Composites Part A-Applied Science and Manufacturing, 2001, 32(5): 683-699.DOI: 10.1016/S1359-835X(00)00149-4.
[5] WHITE S R, SOTTOS N R, GUBELLE P H, et al.Autonomic healing of polymer composites[J].Nature, 2001, 409(6822): 794-797.DOI: 10.1038/35057232.
[6] WHITE S R, CARUSO M M, MOORE J S.Autonomic healing of polymers[J].MRS Bulletin, 2008, 33(8): 766-769.DOI: 10.1557/mrs2008.163.
[7] 郭亚昆, 邹东利, 赵鹏翔, 等.外援型自修复体系及其在环氧基复合材料中的应用[J].材料导报, 2017, 31(1): 72-76.DOI: 10.11896/j.issn.1005-023X.2017.01.009.
GUO Y K, ZOU D L, ZHAO P X, et al.External self-healing systems and their application in epoxy polymers[J].Materials Review, 2017, 31(1): 72-76.
[8] EVERITT D T, LUTERBACHER R, COOPE T S, et al.Optimisation of epoxy blends for use in extrinsic self-healing fibre-reinforced composites[J].Polymer, 2015, 69, 283-292.DOI: 10.1016/j.polymer.2015.02.047.
[9] 杨一林, 卢珣, 王巍巍, 等.热可逆自修复聚氨酯弹性体的制备及表征[J].材料工程, 2017, 45(8): 1-8.DOI: 10.11868/j.issn.1001-4381.2016.000913.
YANG Y L, LU X, WANG W W, et al.Preparation and characterization of thermally reversible self healing polyurethane elastomer[J].Journal of Materials Engineering, 2017, 45(8): 1-8.
[10] 赵凯锋, 张士玉, 王晓飞, 等.一种基于Diels-Alder可逆共价键自修复聚合物的合成及性能[J].高分子材料科学与工程, 2017, 33(12): 8-16.DOI: 10.16865/j.cnki.1000-7555.2017.12.002.
ZHAO K F, ZHANG S Y, WANG X F, et al.Preparation and properties of thermally reversible self-healing polymer based on Diels-Alder reversible covalent bond[J].Polymer Materials Science & Engineering, 2017, 33(12): 8-16.
[11] 龚征宇, 张国平, 孙蓉, 等.基于非共价键的本征型自修复聚合物材料及其应用[J].高分子通报, 2015(4): 1-11.DOI: 10.14028/j.cnki.1003-3726.2015.04.001.
GONG Z Y, ZHANGG P, SUN R, et al.Intrinsic self-healing polymer materials based on non-covalent bond and their applications[J].Polymer Bulletin, 2015(4): 1-11.
[12] TURKENBURG D H, FISCHER H R.Self-healing mechanism based on dispersed solid particles of various monomeric bismaleimides[J].Materials Today Communications, 2016, 8: 148-155.DOI: 10.1016/j.mtcomm.2016.08.004.
[13] RULE J D, SOTTOS N R, WHITE S R.Effect of microcapsule size on the performance of self-healing polymers[J].Polymer, 2007, 48(12): 3520-3529.DOI: 10.1016/j.polymer.2007.04.008.
[14] JONES A S, RULE J D, MOORE J S, et al.Life extension of self-healing polymers with rapidly growing fatigue cracks[J].Journal of the Royal Society Interface, 2007, 4(13): 395-403.DOI: 10.1098/rsif.2006.0199.
[15] JONES A S, RULE J D, MOORE J S, et al.Catalyst morphology and dissolution kinetics of self-healing polymers[J].Chemistry of Materials, 2006, 18(5): 1312-1317.DOI: 10.1021/cm051864s.
[16] BROWN E N, SOTTOS N R, WHITE S R.Fracture testing of a self-healing polymer composite[J].Experimental Mechanics, 2002, 42(4): 372-379.DOI: 10.1007/BF02412141.
[17] BROWN E N, WHITES R, SOTTOS N R.Microcapsule induced toughening in a self-healing polymer composite[J].Journal of Materials Science, 2004, 39(5): 1703-1710.DOI: 10.1023/B:JMSC.0000016173.73733.dc.
[18] BROWN E N, KESSLER M R, SOTTOS N R, et al.In situ poly(urea-formaldehyde)microencapsulation of dicyclopentadiene[J].Journal of Microencapsulation, 2003, 20(6):719-730.DOI: 10.1080/0265204031000154160.
[19] BROWN E N, KESSLER M R, SOTTOS N R.Retardation and repair of fatigue cracks in a microcapsule toughened epoxy composite-Part I: manual infiltration[J].Composites Science and Technology, 2005, 65(15/16): 2466-2473.DOI: 10.1016/j.compscitech.2005.04.020.
[20] KESSLER M R, WHITE S R.Cure kinetics of the ring-opening metathesis polymerization of dicyclopentadiene[J].Journal of Polymer Science: Part A-Polymer Chemistry, 2002, 40(14): 2373-2383.DOI: 10.1002/pola.10317.
[21] SARKAR S, KIM B.Synthesis of graphene oxide-epoxy resin encapsulated urea-formaldehyde microcapsule by in situ polymerization process[J].Polymer Composites, 2018, 39(3):636-644.DOI: 10.1002/pc.23979.
[22] YUAN Y C,RONG M Z,ZHANG M Q, et al.Self-healing polymeric materials using epoxy/mercaptan as the healant[J].Macromolecules, 2008, 41(14): 5197-5202.DOI: 10.1021/ma800028d.
[23] YUAN Y C, RONG M Z, ZHANG M Q, et al.Self-healing of fatigue crack in epoxy materials with epoxy/mercaptan system[J].Express Polymer Letters, 2011, 5(1): 47-59.DOI: 10.3144/expresspolymlett.2011.6.
[24] YIN T, ZHOU L, RONG M Z, et al.Self-healing woven glass fabric/epoxy composites with the healant consisting of micro-encapsulated epoxy and latent curing agent[J].Smart Materials and Structures, 2008, 17(1): 288-294.DOI: 10.1088/0964-1726/17/01/015019.
[25] 童晓梅, 郝芹芹, 闫子英, 等.硅烷改性环氧树脂自修复微胶囊的制备及应用[J].化工进展, 2018, 37(9): 3555-3561.DOI: 10.16085/j.issn.1000-6613.2017-1932.
TONG X M, HAO Q Q, YAN Z Y, et al.Preparation and application of epoxy resin self-healing microcapsules modified by silicone[J].Chemical Industry and Engineering Progress, 2018, 37(9): 3555-3561.
[26] 熊先青, 郭伟娟, 钱文婷, 等.PVC直线封边工序影响因素的研究[J].林产工业, 2017, 44(7): 31-34.DOI: 10.19531/j.issn1001-5299.201707007.
XIONG X Q, GUO W J, QIAN W T, et al.Research of the influence factors on PVC straight-line edge banding process[J].China Forest Products Industry, 2017, 44(7): 31-34.
[27] 梁丰收, 陈卫星, 马爱洁, 等.界面聚合法制备异氰酸酯型微胶囊及其性能[J].高分子材料科学与工程, 2018, 34(2): 150-154.DOI: 10.16865/j.cnki.1000-7555.2018.02.025.
LIANG F S, CHEN W X, MA A J, et al.Property of isocyanate microcapsules prepared by interfacial polymerization[J].Polymer Materials Science & Engineering, 2018, 34(2): 150-154.
[28] YANG J L, KELLER M W, MOORE J S, et al.Microencapsulation of isocyanates for self-healing polymers[J].Macromolecules, 2008, 41(24): 9650-9655.DOI: 10.1021/ma801718v.
[29] CREDICO B D, LEVI M, TURRI S.An efficient method for the output of new self-repairing materials through a reactive isocyanate encapsulation[J].European Polymer Journal, 2013, 49(9): 2467-2476.DOI: 10.1016/j.eurpolymj.2013.02.006.
[30] HUANG M, YANG J.Facile microcapsulation of HDI for self-healing anticorrosion coatings[J].Journal of Materials Chemistry, 2011, 21(30): 11123-11130.DOI: 10.1039/C1JM10794A.
[31] WU G, AN J L, TANG X Z, et al.A versatile approach towards multifunctional robust microcapsules with tunable, restorable, and solvent-proof superhydrophobicity for self-healing and self-cleaning coatings[J].Advanced Functional Materials, 2014, 24(43): 6751-6761.DOI: 10.1002/adfm.201401473.
[32] WU G, AN J L, SUN D W, et al.Robust microcapsules with polyurea/silica hybrid shell for one-part self-healing anticorrosion coatings[J].Journal of Materials Chemistry A, 2014, 2(30): 11614-11620.DOI: 10.1039/c4ta01312c.
[33] SUN D W, AN J L, WU G, et al.Double-layered reactive microcapsules with excellent thermal and non-polar solvent resistance for self-healing coatings[J].Journal of Materials Chemistry A, 2014, 3(8): 4435-4444.DOI: 10.1039/c4ta05339g.
[34] 张路, 王炜, 俞丹, 等.光引发自修复微胶囊的制备及涂层自修复性能[J].高分子材料科学与工程, 2018, 34(2): 116-120.DOI: 10.16865/j.cnki.1000-7555.2018.02.020.
ZHANG L, WANG W, YU D, et al.Preparation and coating self-healing properties of UV-initiated self-healing microcapsules[J].Polymer Materials Science & Engineering, 2018, 34(2): 116-120.
[35] SAMADZADEH M, BOURA S H, PEIKARI M, et al.A review on self-healing coatings based on micro/nanocapsules[J].Progress in Organic Coatings, 2010, 68(3):159-164.DOI: 10.1016/j.porgcoat.2010.01.006.
[36] HASANZADEH M, SHAHIDI M, KAZEMIPOUR M.Application of EIS and EN techniques to investigate the self-healing ability of coatings based on microcapsules filled with linseed oil and CeO2 nanoparticles[J].Progress in Organic Coatings, 2015, 80: 106-119.DOI: 10.1016/j.porgcoat.2014.12.002.
[37] SZABO T, TELEGDI J, NYIKOS L.Linseed oil-filled microcapsules containing drier and corrosion inhibitor-their effects on self-healing capability of paints[J].Progress in Organic Coatings, 2015, 84: 136-142.DOI: 10.1016/j.porgcoat.2015.02.020.
[38] CARUSO M M, DELAFUENTE D A, HO V, et al.Solvent-promoted self-healing epoxy materials[J].Macromolecules, 2007, 40(25): 8830-8832.DOI: 10.1021/ma701992z.
[39] CHO S H, ANDERSSON H M, WHITE S R, et al.Polydimethylsiloxane-based self-healing materials[J].Advanced Materials, 2006, 18(8): 997-1000.DOI: 10.1002/adma.200501814.
[40] 邢瑞英, 张秋禹, 艾秋实, 等.反应性乙烯基硅油/聚脲甲醛自修复微胶囊的制备[J].材料导报, 2009, 23(10): 87-89.DOI: 10.3321/j.issn:1005-023X.2009.10.026.
XING R Y, ZHANG Q Y, AI Q S, et al.Preparation and properties research of self-healing microcapsules of reactive ethylene silicone oil/poly(urea-formaldehyde)[J].Materials Review, 2009, 23(10): 87-89.
[41] ZHANG A, KANG G D, YU H J, et al.From reverse osmosis to nanofiltration: precise control of the pore size and charge of polyamide membranes via interfacial polymerization[J].Desalination, 2019, 466: 16-23.DOI: 10.1016/j.desal.2019.05.001.
[42] 唐璇, 任蕊, 雷珂, 等.原位聚合法制备聚α-烯烃减阻剂微囊的工艺研究[J].应用化工, 2017, 46(12): 2370-2373.DOI:10.16581/j.cnki.issn1671-3206.20170929.004.
TANG X, REN R, LEI K, et al.Study on preparation of coated poly alpha olefin drag reduction agent microcapsules byinsitu polymerization[J].Applied Chemical Industry, 2017, 46(12): 2370-2373.
[43] 汪海平, 胡思前, 张远方.溶剂挥发法制备苯乙烯微胶囊[J].化工新型材料, 2012, 40(3): 52-53.DOI: 10.3969/j.issn.1006-3536.2012.03.016.
WANG H P, HU S Q, ZHANG Y F.Preparation of styrene microcapsules by solvent evaporation method[J].New Chemical Materials, 2012, 40(3): 52-53.
[44] 李海燕, 崔业翔, 王晴, 等.溶剂挥发法制备聚砜包覆桐油自修复微胶囊[J].中国塑料, 2016, 30(5): 34-40.DOI:10.19491/j.issn.1001-9278.2016.05.007.
LI H Y, CUI Y X, WANG Q, et al.Preparation of polysulfone containing tung oil self-healing microcapsules by solvent evaporation method[J].China Plastics, 2016, 30(5): 34-40.
[45] 国栋, 郭虹, 翟玉春.微胶囊技术及其在涂料中的应用[J].材料与冶金学报, 2005, 4(3): 36-39.DOI:10.14186/j.cnki.1671-6620.2005.03.010.
GUO D, GUO H, ZHAI Y C.Application of microcapsule technology in coating[J].Journal of Materials and Metallurgy, 2005,4(3): 36-39.
[46] 曹坤丽, 吴燕, 曹福才, 等.纳米TiO2/硬脂酸超疏水材料的制备与表征[J].林业工程学报, 2017, 2(5): 31-35.DOI:10.13360/j.issn.2096-1359.2017.05.006.
CAO K L, WU Y, CAO F C, et al.Preparation and characterization of nano TiO2/stearicacid surperhydrophobic material[J].Journal of Forestry Engineering, 2017, 2(5): 31-35.
[47] 朱文凯, 吴燕, 曹坤丽, 等.硅溶胶含量对UV固化水性木器涂料漆膜质量的影响[J].林业工程学报, 2016, 1(6): 148-152.DOI:10.13360/j.issn.2096-1359.2016.06.025.
ZHU W K, WU Y, CAO K L, et al.Influence of silica sol content on quality of waterborne UV-curable wood coatings[J].Journal of Forestry Engineering, 2016, 1(6): 148-152.
[48] SIVA T, SATHIYANARAYANAN S.Self healing coatings containing dual active agent loaded urea formaldehyde(UF)microcapsules[J].Progress in Organic Coatings, 2015, 82: 57-67.DOI: 10.1016/j.porgcoat.2015.01.010.
[49] DING X C, RICHTER D L, MATUANA L M, et al.Efficient one-pot synthesis and loading of self-assembled amphiphilic chitosan nanoparticles for low-leaching wood preservation[J].Carbohydrate Polymers, 2011, 86(1):58-64.DOI: 10.1016/j.carbpol.2011.04.002.
[50] 吴落义, 胡智荣, 李玉书,等.低温可逆变色微胶囊的制备及其在水性涂料中的应用研究[J].涂料工业, 2002, 32(12): 17-19.DOI: 10.3969/j.issn.0253-4312.2002.12.007.
WU L Y, HU Z R, LI Y S, et al.Study on the preparation of lower-temperature reversible discoloration microcapsule and the application in water based paint[J].Paint & Coatings Industry, 2002, 32(12): 17-19.
[51] 闫小星, 蔡云婷, 郭伟娟, 等.脲醛@环氧树脂微胶囊的制备及对水性木器涂料的影响[J].林业工程学报, 2019, 4(1): 160-164.DOI:10.13360/j.issn.2096-1359.2019.01.024.
YAN X X, CAI Y T, GUO W J, et al.Preparation of urea-formaldehyde @ epoxy resin microcapsule and its effect on waterborne wood coatings[J].Journal of Forestry Engineering, 2019, 4(1): 160-164.
[52] YAN X X, WANG L, QIAN X Y.Effect of urea-formaldehyde-coated epoxy microcapsule modification on gloss, toughness and chromatic distortion of acrylic copolymers waterborne coating[J].Coatings, 2019, 9(4):1-14.DOI: 10.3390/coatings9040239.
[53] HE S, LIN L, FU F, et al.Microwave treatment for enhancing the liquid permeability of Chinese fir[J].BioResources, 2014, 9(2): 1924-1938.DOI:10.15376/biores.9.2.1924-1938.
[54] JEONG S G, JIEON J, SEO J, et al.Performance evaluation of the microencapsulated PCM for wood-based flooring application[J].Energy Conversion & Management, 2012, 64: 516-521.DOI: 10.1016/j.enconman.2012.03.007.
[55] 胡拉, 吕少一, 傅峰, 等.微胶囊技术在木质功能材料中的应用及展望[J].林业科学, 2016, 52(7): 148-157.DOI: 10.11707/j.1001-7488.20160718.
HU L, LYU S Y, FU F, et al.Review of application of microencapsulation in wood functional materials and its future trends[J].Scientia Silvae Sinicae, 2016, 52(7): 148-157.
[56] 陈健, 潘国祥, 李顺利, 等.制备条件对羟基氧化铝包覆氧化铁黄颜料耐热性能的影响[J].中国粉体技术, 2016, 22(1): 48-51.DOI:10.13732/j.issn.1008-5548.2016.01.011.
CHEN J, PAN G X, LI S L, et al.Effect of preparing condition on heat resistance property of iron oxide yellow pigment coated with hydroxyl alumina[J].China Powder Science and Technology, 2016, 22(1): 48-51.
[57] 梅约, 方珑文, 徐利昆.单变色不可逆示温涂料的研制[J].涂料工业, 2002, 32(5): 15-19.DOI: 10.3969/j.issn.0253-4312.2002.05.006.
MEI Y, FANG L W, XU L K.Development of single color irreversible temperature indicating paint[J].Paint & Coatings Industry, 2002, 32(5): 15-19.
[58] 张妍妍, 殷允杰, 王潮霞.乳化-化学交联法光致变色微胶囊的制备及其性能[J].精细化工, 2018, 35(10): 1636-1640.DOI: 10.13550/j.jxhg.20170488.
ZHANG Y Y, YIN Y J, WANG C X.Preparation and properties of photochromic microcapsule via emulsification-chemical cross-linking method[J].Fine Chemicals, 2018, 35(10): 1636-1640.
[59] 万义玲, 麦东彬, 张琪, 等.新型保温建筑涂料用微胶囊乳液的制备[J].涂料工业, 2010, 40(11): 27-31.DOI: 10.3969/j.issn.0253-4312.2010.11.007.
WAN Y L, MAI D B, ZHANG Q, et al.Preparation of new type microcapsule latex used for heat insulation coatings[J].Paint & Coatings Industry, 2010, 40(11): 27-31.
[60] SONG Y K, JO Y H, LIM Y J, et al.Sunlight-induced self-healing of a microcapsule-type protective coating[J].ACS Applied Materials & Interfaces, 2013, 5(4): 1378-1384.DOI: 10.1021/am302728m.
[61] DONG B Q, WANG Y S, DING W J, et al.Electrochemical impedance study on steel corrosion in the simulated concrete system with a novel self-healing microcapsule[J].Construction & Building Materials, 2014, 56: 1-6.DOI: 10.1016/j.conbuildmat.2014.01.070.
[62] GUO W C, JIA Y, TIAN, KS, et al.UV-triggered self-healing of a single robust SiO2 microcapsule based on cationic polymerization for potential application in aerospace coatings[J].ACS Applied Materials & Interfaces, 2016, 8(32): 21046-21054.DOI:10.1021/acsami.6b06091.
[63] LIU Y, SHAO X Q, HUANG J, et al.Flame sprayed environmentally friendly high density polyethylene(HDPE)-capsaicin composite coatings for marine antifouling applications[J].Materials Letters, 2018, 238: 46-50.DOI: 10.1016/j.matlet.2018.11.144.
[64] PEREZ M, BLUSTEIN G, GARCIA M, et al.Cupric tannate: a low copper content antifouling pigment[J].Progress in Organic Coatings, 2006, 55(4): 311-315.DOI: 10.1016/j.porgcoat.2005.11.014.
[65] LIU C, MA C F, XIE Q Y, et al.Self-repairing silicone coatings for marine anti-biofouling[J].Journal of Materials Chemistry A, 2017, 5(30): 15855-15861.DOI: 10.1039/c7ta05241c.

相似文献/References:

[1]于再君,吴智慧*,苏团.家具用竹集成材涂料渗透性微观结构分析[J].林业工程学报,2016,1(02):130.[doi:10.13360/j.issn.2096-1359.2016.02.023]
 YU Zaijun,WU Zhihui*,SU Tuan.Microstructure analysis of the coating permeability of laminated bamboo panel for furniture[J].Journal of Forestry Engineering,2016,1(05):130.[doi:10.13360/j.issn.2096-1359.2016.02.023]
[2]闫小星,蔡云婷,郭伟娟,等.脲醛@环氧树脂微胶囊的制备及对水性木器涂料的影响[J].林业工程学报,2019,4(01):160.[doi:10.13360/j.issn.2096-1359.2019.01.024]
 YAN Xiaoxing,CAI Yunting,GUO Weijuan,et al.Preparation of urea-formaldehyde@epoxy resin microcapsule and its effect on waterborne wood coatings[J].Journal of Forestry Engineering,2019,4(05):160.[doi:10.13360/j.issn.2096-1359.2019.01.024]

备注/Memo

备注/Memo:
收稿日期:2018-09-28 修回日期:2019-07-02
基金项目:江苏省自然科学青年基金(BK20150887); 江苏省高校自然科学研究项目(14KJB220007)。
作者简介:闫小星,女,副教授,研究方向为变色涂料。E-mail:yanxiaoxing@njfu.edu.cn
更新日期/Last Update: 2019-09-10